Galvanic Cells: Zinc-Copper Example, Notation, and Cell Potential

Generated from prompt:

Write notes on galvanic cell, using zinc-copper cell as example. Determining the cell potential and cell notation

This presentation introduces galvanic cells, which generate electricity from spontaneous redox reactions. Using the classic zinc-copper cell as an example, it covers cell components, half-cell reactions (Zn oxidation at anode, Cu reduction at cathode), cell notation (Zn | Zn²⁺ || Cu²⁺ | Cu), standard reduction potentials, and cell potential calculation (E°_cell = 1.10 V). Includes agenda, diagrams, and key takeaways on electrochemical principles foundational to batteries.

May 13, 202612 slides
Slide 1 of 12

Slide 1 - Zinc-Copper Cell Example Cell Potential & Notation

Zinc-Copper Cell Example Cell Potential & Notation

Notes on Electrochemical Principles

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Photo by Stephan HK on Unsplash

Slide 1 - Zinc-Copper Cell Example
Cell Potential & Notation
Slide 2 of 12

Slide 2 - Presentation Outline

  • What is a Galvanic Cell?
  • Zinc-Copper Cell Example
  • Half-Cell Reactions
  • Cell Notation
  • Cell Potential Calculation
  • Conclusion

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Slide 2 - Presentation Outline
Slide 3 of 12

Slide 3 - Galvanic Cell Fundamentals

1

What is a Galvanic Cell

Generates electricity from spontaneous redox reactions

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Slide 3 - Galvanic Cell Fundamentals
Slide 4 of 12

Slide 4 - Definition and Components

  • Generates electric current from spontaneous oxidation–reduction (redox) reactions
  • Two half-cells: each metal immersed in its respective metal ions solution
  • Connected by salt bridge or porous membrane
  • Named after Luigi Galvani and Alessandro Volta
  • Example: Two different metals in separate beakers

Source: Wikipedia: Galvanic cell

Slide 4 - Definition and Components
Slide 5 of 12

Slide 5 - Zinc-Copper Example

2

Zinc-Copper Cell

Classic galvanic cell demonstration

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Photo by Logan Voss on Unsplash

Slide 5 - Zinc-Copper Example
Slide 6 of 12

Slide 6 - Zinc-Copper Galvanic Cell

  • Zinc anode oxidizes: Zn → Zn²⁺ + 2e⁻
  • Copper cathode reduces: Cu²⁺ + 2e⁻ → Cu
  • Salt bridge maintains charge balance
  • Electrons flow externally from anode to cathode

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Photo by Claudio Schwarz on Unsplash

Slide 6 - Zinc-Copper Galvanic Cell
Slide 7 of 12

Slide 7 - Half-Cell Reactions

Anode (Oxidation) Zn(s) → Zn²⁺(aq) + 2e⁻ Less noble metal (Zn) loses electrons

Cathode (Reduction) Cu²⁺(aq) + 2e⁻ → Cu(s) More noble metal (Cu) gains electrons

Slide 7 - Half-Cell Reactions
Slide 8 of 12

Slide 8 - Cell Notation

  • Convention: Anode | Anode²⁺(aq) || Cathode²⁺(aq) | Cathode
  • Zinc-Copper: Zn(s) | Zn²⁺(aq) || Cu²⁺(aq) | Cu(s)
  • | = phase boundary (solid|liquid)
  • || = salt bridge or porous junction
  • Anode on left (oxidation), cathode on right (reduction)
Slide 8 - Cell Notation
Slide 9 of 12

Slide 9 - Cell Potential

4

Determining Cell Potential

Using standard electrode potentials

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Slide 9 - Cell Potential
Slide 10 of 12

Slide 10 - Standard Reduction Potentials

ElectrodeHalf-Reaction (Reduction)E° (V)
Zn²⁺/ZnZn²⁺ + 2e⁻ → Zn-0.76
Cu²⁺/CuCu²⁺ + 2e⁻ → Cu+0.34

Source: Wikipedia: Galvanic series

Slide 10 - Standard Reduction Potentials
Slide 11 of 12

Slide 11 - Calculating E_cell

  • cell = E°cathode (reduction) - E°anode (reduction)
  • cell = 0.34 V (Cu) - (-0.76 V) (Zn) = 1.10 V
  • Positive E°_cell: spontaneous reaction
  • Zinc (more negative potential) acts as anode

Source: Wikipedia: Galvanic series

Slide 11 - Calculating E_cell
Slide 12 of 12

Slide 12 - Key Takeaways

Galvanic Cell: Spontaneous redox generates electricity Zinc-Copper Example:

  • Notation: Zn | Zn²⁺ || Cu²⁺ | Cu
  • cell = 1.10 V (0.34 - (-0.76))

Foundation of batteries and electrochemical applications

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Photo by Jorge Campos on Unsplash

Slide 12 - Key Takeaways

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